Lawrence, NS, Banks, CE, Tustin, GJ, Jones, TGJ, Smith, RB, Davis, J and Wadhawan, JD (2007) Electrochemical characterisation of novel water-soluble ruthenocene complexes: An anion-dependent response. ELECTROCHEMISTRY COMMUNICATIONS, 9 (7). pp. 1451-1455. [Journal article]
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The synthesis and voltammetric exploration of water-soluble ruthenocene sulfonate is reported. H-1 and C-13 NMR, mass spectroscopy and elemental analysis data are given to confirm the successful synthesis of this novel compound. Furthermore, it is found that the cyclic voltammetric response is strongly dependent on the size of anion in solution. Sodium toluene sulfonate is found to be capable of forming a charge-transfer complex with the oxidized ruthenocenium ion. In the presence of all other anions, follow-on reactions are observed. (c) 2007 Elsevier B.V. All rights reserved.
|Item Type:||Journal article|
|Faculties and Schools:||Faculty of Computing & Engineering|
Faculty of Computing & Engineering > School of Engineering
|Research Institutes and Groups:||Engineering Research Institute|
Engineering Research Institute > Nanotechnology & Integrated BioEngineering Centre (NIBEC)
|Deposited By:||Professor James Davis|
|Deposited On:||01 Jul 2010 08:11|
|Last Modified:||18 Aug 2011 10:19|
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