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Studies on Thermokinetic Methods (I) Determination of Reaction Rate Constants and Activation Energies by Calorimetry

Xie, Chang Li, Xu, Quiduan, Qu, Songsheng and Owusu, RK (1986) Studies on Thermokinetic Methods (I) Determination of Reaction Rate Constants and Activation Energies by Calorimetry. Acta Physicochimica Sinica, 2 . pp. 363-369. [Journal article]

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URL: http://en.cnki.com.cn/Article_en/CJFDTOTAL-WLHX198604015.htm

Abstract

The esterification rate constants of the acetic acid with the methanol and ethanol at various temperatures were determined by the flow microcalorimetry, while with the help of Arrhenius relation the activation energies of these reactions were determined. In order to check the reliability of method, the hydrolysis (reversal reaction of esterification) rate constants of methyl and ethyl acetates were determined, the results of experiments are consistent with results of calculation from the data of esterification experiments.

Item Type:Journal article
Faculties and Schools:Faculty of Life and Health Sciences > School of Biomedical Sciences
Faculty of Life and Health Sciences
Research Institutes and Groups:Biomedical Sciences Research Institute > Northern Ireland Centre for Food and Health (NICHE)
Biomedical Sciences Research Institute
ID Code:20961
Deposited By: Dr Richard Owusu-Apenten
Deposited On:23 Feb 2012 14:17
Last Modified:16 Mar 2015 16:04

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