Smyth, Franklin and JAN, MR (1993) A STUDY OF THE DIFFERENTIAL-PULSE VOLTAMMETRIC BEHAVIOR OF ORGANIC AND INORGANIC SELENIUM-COMPOUNDS AND ITS ANALYTICAL APPLICATIONS. FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 346 (10-11). pp. 947-951. [Journal article]
Full text not available from this repository.
Abstract
N-(1-methylpropyl)-2-phenylselenenyl-2-phenyl-butyramide(I), N-(1-methylpropyl)-2-phenylselenenyl-2-phenylacetamide(II), N-(isopropyl)-2-phenylselenenyl-2-phenylacetamide(III) and diphenyldiselenide(IV) undergo homolytic fission of their Se-C bonds (and in the latter case the Se-Se bond) followed by formation of adsorbable Ph-Se-Hg at the stationary mercury drop electrode. Ph-Se-Hg can then be cathodically stripped with LODs of 9 . 10(-9) mol/l, 3.6 . 10(-8) mol/l, 1.4 . 10(-8) mol/l and 10(-8) mol/l, respectively. Selenium(IV) can be determined by formation of adsorbable HgSe with an LOD of 5 . 10(-10) mol/l. Differential pulse voltammetry with adsorptive preconcentration of the reducible species cannot discriminate between the studied organoselenium compounds (I)-(IV) or between the organoselenium compounds and Se(IV), due to the similarity of electrode processes.
Item Type: | Journal article |
---|---|
Faculties and Schools: | Faculty of Life and Health Sciences Faculty of Life and Health Sciences > School of Biomedical Sciences |
Research Institutes and Groups: | Biomedical Sciences Research Institute Biomedical Sciences Research Institute > Pharmacy & Pharmaceutical Sciences |
ID Code: | 3729 |
Deposited By: | Prof W.Franklin Smyth |
Deposited On: | 12 Jan 2010 09:37 |
Last Modified: | 04 May 2012 08:20 |
Repository Staff Only: item control page